WebMar 2, 2024 · Significance. Like thiols, boronic acids are unstable to oxidation in biological contexts, limiting their utility. We discovered that the rate-limiting step in the oxidation of a boronic acid can be slowed by the installation of a pendant carboxyl group that is a ligand to the boron atom. The ensuing boronic acid is 10,000-fold more resistant ... WebIn this study, by exploiting the coordination ability of borate ions with polyol molecules, we report enhanced and selective electrochemical oxidation of glycerol to ∼85% C₃ …
Electrochemical Oxidation of Glycerol to …
WebOct 22, 2024 · In this study, by exploiting the coordination ability of borate ions with polyol molecules, we report enhanced and selective electrochemical oxidation of glycerol to ∼85% C 3 chemicals (67% for … WebMar 24, 2024 · The glycerol oxidation reaction (GOR) has high potential in substituting the oxygen evolution reaction (OER) in electrochemical water splitting, enabling the synthesis of value-added organic products. ... Huang et al. found that adding borate ions to the alcohol-containing electrolyte allowed the coordination with glycerol, ... svjetlana
Direct and Indirect Electrooxidation of Glycerol to …
WebAlso, an unprecedented selectivity in glycerol electrooxidation towards two products of high interest, formate (66%) and glycolate (32%), has been … WebSep 6, 2024 · Therefore in this study, corn starch was thermally processed with urea and borate in a water medium. The pure starch (PS), starch-urea (SU), starch-borate (SB), and starch-urea-borate (SUB) samples were prepared and characterized for their rheological traits. The PS sample exhibited a peak viscosity of 299 cP after 17 min of thermal … WebAccording to the literature, many small molecules containing hydroxyl groups, such as glycerol and sorbitol, have the ability to plasticize PVAc. 34,35 Therefore, boric acid, which is present in all PVAc/borate samples … baseball 30/30